منابع مشابه
XAFS study of gadolinium and samarium bisporphyrinate complexes.
The comparative X-ray absorption spectroscopy study of gadolinium and samarium bisporphyrinate complexes represented by the formulas Gd(III)H(oep)(tpp), Gd(III)(oep)(2), Gd(III)H(tpp)(2) and Sm(III)H(oep)(tpp), Sm(III)(oep)(2), Sm(III)H(tpp)(2) is reported. The XAFS spectra are recorded on the LURE-DCI storage ring (Orsay, France) in transmission mode on the microcrystalline samples at the Gd a...
متن کاملXAFS study of niobium oxide on alumina
The structure of the niobium oxide on alumina surface was investigated for low loading (5 wt.-%) and high loading (19 wt.-%) samples. The TPD profile of water molecules showed the appearance of water adsorption sites other than those on alumina. The XANES and EXAFS spectra clearly showed that niobic acid-like species are formed on the surface of 19 wt.-% NbO,/Al,O,. The XANES spectra of 5 wt.-%...
متن کاملThe Use of XAFS to Distinguish between Inner- and Outer-Sphere Lead Adsorption Complexes on Montmorillonite.
Adsorption mechanisms of Pb on montmorillonite were investigated by conducting equilibrium and X-ray absorption fine structure (XAFS) spectroscopy studies. Data from the batch equilibrium studies indicate that Pb could be adsorbing via two mechanisms, depending on ionic strength. At low ionic strength (I = 0.006 M) Pb adsorption is pH-independent: 97% of the available Pb was removed from soluti...
متن کاملXAFS Study of Arsenical Nickel Hydroxide
To Investigate the role played by nickel co-ions in contributing to the stability of arsenic, fluorescence XAFS measurements at both arsenic K-edge and nickel K-edge, respectively, on amorphous arsenical nickel hydroxide, crystalline arsenical nickel hydroxide, and annabergite reference compounds have been carried out. The XAFS results indicate that the arsenic-bearing nickel hydroxides have a ...
متن کاملNovel FeII and CoII Complexes of Natural Product Tryptanthrin: Synthesis and Binding with G-Quadruplex DNA
Tryptanthrin is one of the most important members of indoloquinoline alkaloids. We obtained this alkaloid from Isatis. Two novel FeII and CoII complexes of tryptanthrin were first synthesized. Single-crystal X-ray diffraction analyses show that these complexes display distorted four-coordinated tetrahedron geometry via two heterocyclic nitrogen and oxygen atoms from tryptanthrin ligand. Binding...
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ژورنال
عنوان ژورنال: Japanese Journal of Applied Physics
سال: 1993
ISSN: 0021-4922,1347-4065
DOI: 10.7567/jjaps.32s2.809